The pH of 0.50 M benzoic acid is 2.24. Calculate the change in pH when 2.64 g of C6H5COONa is added to 38 mL of 0.50 M benzoic acid, C6H5COOH. Ignore any changes in volume. The Ka value for C6H5COOH is 6.5 x 10-5.

Respuesta :

Answer:

1.93

Explanation:

Moles of C[tex]_{6}[/tex]H[tex]_{5}[/tex]COOH = 38/1000 × 0.50 = 0.019mol

Moles of C[tex]_{6}[/tex]H[tex]_{5}[/tex]COONa = Mass/Molar mass = 2.64/144.10 = 0.018321mol

Final pH = pKa + log([C[tex]_{6}[/tex]H[tex]_{5}[/tex]COONa]/[C[tex]_{6}[/tex]H[tex]_{5}[/tex]COOH]

= -log Ka  + log(mols of C[tex]_{6}[/tex]H[tex]_{5}[/tex]COONa]/mols of C[tex]_{6}[/tex]H[tex]_{5}[/tex]COOH

= -log(6.5 × 10^(-5)) + log (0.018321/0.019)=4.17

change in pH = final - initial pH

= 4.17 - 2.24

=1.93

pH is the depiction of the acidity and basicity of the solution and can range from 0 to 14 on the pH scale. The change in pH of benzoic acid is 1.93.

What is pH?

pH is the concentration of the hydrogen ion in the solution depicting the acidity and the basicity of the solution.

Calculate moles of Benzoic acid as:

[tex]\begin{aligned}\rm moles &= \dfrac{\rm mass}{\rm molar \;mass}\\\\&=\dfrac{38}{1000}\times 0.50\\\\&= 0.019\;\rm mol\end{aligned}[/tex]

Calculate moles of Sodium benzoate as:

[tex]\begin{aligned}\rm moles &= \dfrac{\rm mass}{\rm molar \;mass}\\\\&=\dfrac{2.64}{144.10}\\\\&= 0.01832\;\rm mol\end{aligned}[/tex]

pH can be calculated as:

[tex]\begin{aligned}\rm pH &= \rm pKa + log\dfrac{([C_{6}H_{5}COONa]}{[C_{6}H_{5}COOH]}\\\\&= \rm -log(6.5 \times 10^{-5}) + log (\dfrac{0.018321}{0.019})\\\\&= 4.17\end{aligned}[/tex]

Change in the pH can be calculated as:

[tex]\begin{aligned} \rm pH &= \rm final - initial \; pH\\\\&= 4.17 - 2.24\\\\&=1.93\end{aligned}[/tex]

Therefore, 1.93 is the change in the pH of benzoic acid.

Learn more about pH here:

https://brainly.com/question/7578224