Respuesta :
Answer:
- 12.1
Explanation:
M(C3H8O3) = 3*12.0 + 8*1.0 + 3*16.0 = 92 g/mol
210.0 g C3H8O3 * 1 mol C3H8O3/92 g C3H8O3 = 210/92 mol C3H8O3
350.g = 0.350 kg H2O
Molality = mol soluty/ kg solvent = (210/92 mol C3H8O3) /(0.350 kg H2O) = =6. 522 molal
ΔT =i* Kf* m
(T2 - T1) = i* Kf* m
(T2 - 0°C) = 1*(-1.86°C/molal *6.522 molal)
T2= - 12.1°C
The change in freezing point and the new freeze point are -12.1°C and -12.1°C.
Given the following data:
- Mass of glycerol = 210.0 grams
- Mass of water = 350.0 grams to kg = 0.35 kg
- Chemical formula of glycerol = [tex]C_3H_8O_3[/tex]
- Freezing point depression constant for water, Kf = 0.512 °C/m
We know that the temperature at which water freezes is 0°C.
To determine the change in freezing point and the new freeze point:
First of all, we would determine the molar mass of glycerol:
Molar mass of glycerol ([tex]C_3H_8O_3[/tex]) = [tex]12 \times (1 \times 8)\times (16 \times 3)[/tex]
Molar mass of glycerol ([tex]C_3H_8O_3[/tex]) = [tex]12 \times (8)\times (48)[/tex]
Molar mass of glycerol ([tex]C_3H_8O_3[/tex]) = 92 g/mol.
Next, we would find the number of moles of glycerol that is required:
[tex]Number\;of\;moles = \frac{mass}{molar\;mass}\\\\Number\;of\;moles = \frac{210.0}{92}[/tex]
Number of moles = 2.28 moles
To find the molality concentration:
[tex]Molality = \frac{moles\;of \;solute}{mass\;of \;solvent} \\\\Molality = \frac{2.28}{0.35}[/tex]
Molality = 6.51 molal.
Mathematically, the freezing point elevation of a liquid is given by the formula:
[tex]\Delta T = K_f m[/tex]
Where:
- [tex]\Delta T[/tex] is the change in temperature.
- Kf is the molal freezing point constant.
- m is the molality of solution.
Substituting the parameters into the formula, we have;
[tex]\Delta T = -1.86 \times 6.51[/tex]
Change in temperature = -12.1°C.
Now, we can determine the new freeze point:
[tex]\Delta T = T_n - T_f\\\\T_n = \Delta T + T_f\\\\T_n = -12.1 + 0[/tex]
New freeze point = -12.1°C.
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