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Calculate the free energy change for the reaction:
2 NO(g) + O2(g) → 2 NO2(g)
(A) - 9.3 kcal
(B) + 24.9 kcal
(C) + 9.3 kcal
(D) - 16.6 kcal
(E) + 16.6 kcal​

Calculate the free energy change for the reaction2 NOg O2g 2 NO2gA 93 kcalB 249 kcalC 93 kcalD 166 kcalE 166 kcal class=

Respuesta :

sebassandin

Answer:

(D) - 16.6 kcal

Explanation:

Hello,

In this case, the Gibbs free energy for the given reaction is computed in terms of the Gibbs free energy of formation of each species involved in the chemical reaction:

[tex]\Delta _rG=2\Delta _fG_{NO_2}-2\Delta _fG_{NO}-\Delta _fG_{O_2}[/tex]

Thus, it is found for nitrogen monoxide, oxygen and nitrogen dioxide the following Gibbs free energies of formation: 87.6, 0 and 51.3 kJ/mol respectively, therefore we compute:

[tex]\Delta _rG=2(51.3kJ/mol)-2(87.6kJ/mol)=-72.6kJ*\frac{1kcal}{4.184kJ} \\\\\Delta _rG=-17.35kcal[/tex]

The closest result is (D) - 16.6 kcal, as such difference is noticed when different sources for thermochemical data are used, in this case, the NIST data were used.

Best regards.

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