Fe3+(yellow) + SCN-(colorless) <--> [FeSCN]2+(dark red)
If Fe3+ is added to the solution the solution turns darker red
While precipitating out Fe3+ (as Fe(OH)3) or SCN- (as AgSCN) will push the equilibrium to the left, consuming the complex and reducing color intensity, the addition of Fe3+ or SCN- will push the equilibrium to the right, creating more complex and intensifying the color.
The pace of reaction rises as Fe3+ levels rise. The concentration of SCN reduces as the rate rises.
The FeSCN2+ complex, which is created when iron(III) and thiocyanate ions react, displays an extremely strong blood red color (or orange in diluted solution), making it simple to detect and quantify using spectrophotometry.
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