No two electrons in an atom or molecule may have the same four electronic quantum numbers, according to the Pauli Exclusion Principle. Only two electrons can fit into an orbital at a time, hence they must have opposing spins.
According to Pauli's Exclusion Principle, no two electrons in the same atom can have values for all four of their quantum numbers that are exactly the same. In other words, two electrons in the same orbital must have opposing spins and no more than two electrons can occupy the same orbital.
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