Q1)
We have been given the OH⁻ concentration, therefore we first need to find the pOH value and then the pH value.
pOH = -log [OH⁻]
pOH = -log (0.225 M)
pOH = 0.65
pH + pOH = 14
pH = 14 - 0.65 = 13.35
Q2)
pOH = -log[OH⁻]
pOH = -log (0.0015 M)
pOH = 2.82
pH + pOH = 14
pH = 14 - 2.82
pH = 11.18